Regiochemical Control in the Preparation of 2-(Nosyloxy) β,γ-Unsaturated Esters and 4-(Nosyloxy) α,β-Unsaturated Esters from 1--1-alkoxy 1,3-Dienes

DOI: 10.1021/jo00003a022

Source and publish data:

Journal of Organic Chemistry p. 1014 - 1019 (1991)

Update date:2022-08-05

Topics:

Authors:

Hoffman, Robert V.

Kim, Hwa-Ok

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Article abstract of DOI:10.1021/jo00003a022

A series of 1-<(trialkylsilyl)oxy>-1-alkoxy 1,3-dienes 1a-i were found to react with p-nitrobenzenesulfonyl peroxide in the presence of sodium methoxide or zinc chloride to give alkyl 2 -<<(p-nitrophenyl)sulfonyl>oxy> β,γ-unsaturated esters 3 and 4-<<(p-n

Full text of DOI:10.1021/jo00003a022

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