Syntheses and Rearrangements of Spirocyclic Oxaziridines Derived from Unsymmetrical Ketones

DOI: 10.1021/jo00002a006

Source and publish data:

Journal of Organic Chemistry p. 499 - 508 (1991)

Update date:2022-08-05

Topics:

Authors:

Aube, Jeffrey

Hammond, Marlys

Gherardini, Elyse

Takusagawa, Fusao

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Article abstract of DOI:10.1021/jo00002a006

Oxaziridines provide useful alternatives to the Beckmann rearrangement and Schmidt reaction for ring enlargement of cyclic ketones.The procedure involves the condensation of the ketone in question with optically active α-methylbenzylamine, oxidation of th

Full text of DOI:10.1021/jo00002a006

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