Syntheses and Rearrangements of Spirocyclic Oxaziridines Derived from Unsymmetrical Ketones

DOI: 10.1021/jo00002a006

Source and publish data:

Journal of Organic Chemistry p. 499 - 508 (1991)

Update date:2022-08-05

Topics:

Authors:

Aube, Jeffrey

Hammond, Marlys

Gherardini, Elyse

Takusagawa, Fusao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00002a006

Oxaziridines provide useful alternatives to the Beckmann rearrangement and Schmidt reaction for ring enlargement of cyclic ketones.The procedure involves the condensation of the ketone in question with optically active α-methylbenzylamine, oxidation of th

Full text of DOI:10.1021/jo00002a006

Products guided by the article

Product name:(R)-3-Phenyl-1-((R)-1-phenyl-ethyl)-azepan-2-one

Cas No:131514-22-2

R&D Labs maybe for 131514-22-2

Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Aqua Chem Industry Co., Ltd

Contact:+86-515-88356562

Address:No.2, West Daqing Road, Yancheng, Jiangsu, China

Relevant to this article

Reactions of allyloxy(methoxy)carbene in solution. Carbene rearrangement and Claisen rearrangement of the carbene dimer

Doi:10.1016/j.tet.2005.04.024
(2005)
Synthesis of 4-methoxy and 5-methoxy substituted 7-aza-isoindolin-1-ones

Doi:10.3987/COM-13-12785
(2013)
Quaternary α,α-2-oxoazepane α-amino acids: Synthesis from ornithine-derived β-lactams and incorporation into model dipeptides

Doi:10.1021/jo200894d
(2011)
Synthesis and Biological Evaluation of Novel Triazole Derivatives as Strigolactone Biosynthesis Inhibitors

Doi:10.1021/acs.jafc.9b01276
(2019)
A Suzuki-type cross-coupling reaction of arylacetylene halides with arylboronic acids

Doi:10.1002/aoc.1795
(2011)
Gold-catalyzed cycloisomerizations of 1-(2-(Tosylamino)phenyl)prop-2-yn-1- ols to 1H-Indole-2-carbaldehydes and (E)-2-(Iodomethylene)Indolin-3-ols

Doi:10.1021/jo201208e
(2011)

Article Doi