Journal of the Chemical Society. Perkin transactions I p. 2835 - 2840 (1990)
Update date:2022-08-04
Topics:
Nemoto, Hideo
Ishibashi, Hiroki
Mori, Masahiko
Fujita, Shigekazu
Fukumoto, Keiichiro
A novel and convenient route to chiral cyclobutanones (8) and (9) by ring expansion of the cyclopropylmethanols (6) and (7) was developed, leading to an enantioselective total synthesis of (R)-(+)-dodecan-5-olide (25), and (S)-(+)- and (R)-(-)-5-<(Z)-dec-1-enyl>dihydrofuran-2(3H)-one (35) and (36) (the pheromone of the Japanese beetle).
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