
Tetrahedron p. 2943 - 2964 (1990)
Update date:2022-08-05
Topics:
Hogan, Iain
Jenkins, Paul D.
Sainsbury, Malcolm
A new construction of unsymmetrically 1,4-disubstituted carbazoles has been devised and used in the synthesis of the alkaloid olivacine.The starting materials are gramines and the sodium salts of 2-cyano-4-oxopentanonitriles.These afford 4-cyano-5-(indol-
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