Synthesis of optically active cyclobutanones by the photolysis of chromium-alkoxycarbene complexes in the presence of optically active ene-carbamates

DOI: 10.1021/ja00003a027

Source and publish data:

Journal of the American Chemical Society p. 923 - 927 (1991)

Update date:2022-08-05

Topics: Synthesis Optically active Photolysis Experimental Presence Cyclobutanones

Authors:

Hegedus, Louis S.

Bates, Roderick W.

S?derberg, Bj?rn C.

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Article abstract of DOI:10.1021/ja00003a027

Optically active ene-carbamates derived from (S)-phenylglycine were allowed to photochemically react with à variety of (alkoxy)(alkyl)chromium-carbene complexes. Cyclobutanones were formed in fair to good yield with generally excellent control of stereoch

Full text of DOI:10.1021/ja00003a027

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