Synthesis of 4-O-methyl-β-rhodomycins using derivatives of 4-amino-4-deoxy- and 3,4-diamino-3,4-dideoxy sugars

Article abstract of DOI:10.1016/0008-6215(90)80086-I

Synthesis of 7-O-(4-amino-2,4,6-trideoxy- and 7-O-(3,4-diamino-2,3,4,6-tetradeoxy-α-L-lyxo-hexopyranosyl)-4-O-methyl-β-rhodomycinones (31 and 33) are described.The glycosyl donors 2,4,6-trideoxy-1,3-di-O-p-nitrobenzoyl-4-trifluoroacetamido-β-L-lyxo-hexopy