Palladium-Catalyzed Regio- and Stereoselective Aryldesilylation of α-Silylstyrenes with Arenediazonium Salts

DOI: 10.1246/cl.1988.873

Source and publish data:

Chemistry Letters p. 873 - 876 (1988)

Update date:2022-08-02

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Authors:

Ikenaga, Kazutoshi

Matsumoto, Satoshi

Kikukawa, Kiyoshi

Matsuda, Tsutomu

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Article abstract of DOI:10.1246/cl.1988.873

α-Trialkylsilylstyrenes easily reacted with arenediazonium tetrafluoroborates+ BF4^- (4)> to give (E)-PhCH=CHAr under palladium(0) catalysis.The bulky substituents on silicon gave better stereoselectivity.

Full text of DOI:10.1246/cl.1988.873

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