Detection of Carbonyl Oxide from Singlet p-Nitrophenylchlorocarbene and Oxygen

DOI: 10.1039/c39900001482

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1482 - 1483 (1990)

Update date:2022-08-02

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Authors:

Liu, Michael T. H.

Bonneau, Roland

Jefford, Charles W.

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Article abstract of DOI:10.1039/c39900001482

p-Nitrophenylchlorocarbene reacts with oxygen with a rate constant 2.24<*>10⁷ M^-1 s^-1 in isooctane at 25 deg C giving rise to an intermediate carbonyl oxide which absorbs at 400 nm.

Full text of DOI:10.1039/c39900001482

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