Electrophilic Substitution at an Olefinic Carbon Atom. Some Studies of the Mechanism of the Trifluoroacetylation of Aryl Vinyl Sulfides

DOI: 10.1021/jo00006a001

Source and publish data:

Journal of Organic Chemistry p. 1975 - 1976 (1991)

Update date:2022-08-02

Topics:

Authors:

Hojo, Masaru

Masuda, Ryoichi

Kamitori, Yasuhiro

Okada, Etsuji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00006a001

A study of the mechanism of the trifluoroacetylation of aryl vinyl sulfides was made.The rates of trifluoroacetylation of ArSCH=CH2, ArSCH=CD2, cis-ArSCH=CHD, and trans-ArSCH=CHD were determined.The results imply that this electrophilic substitution reaction proceeds by a single-step mechanism.

Full text of DOI:10.1021/jo00006a001

Products guided by the article

Product name:C₈H₆⁽²⁾H₂S

Cas No:132461-65-5

R&D Labs maybe for 132461-65-5

Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark

Relevant to this article

A Copper(II) Tetephthalato Derivative Ordering Ferromagnetically at T_c = 13 K

Doi:10.1039/c39900001771
(1990)
Synthesis and antitrypanosomal activities of novel pyridylchalcones

Doi:10.1016/j.ejmech.2017.01.027
(2017)
SYNTHESIS AND ANTIVIRAL ACTIVITY OF 2-ANILINOMETHYL DERIVATIVES OF 5-HYDROXYINDOLE

Doi:10.1007/BF00766550
(1990)
Synthesis and reactivity of molybdenum complexes containing functionalized alkynyl ligands: A photochemically activated CO-releasing molecule (PhotoCO-RM)

Doi:10.1021/om200495h
(2011)
Reduced nitrogen hydride complexes of a cofacial metallodiporphyrin and their oxidative interconversion. an analysis of ammonia oxidation and prospects for a dinitrogen electroreduction catalyst based on cofacial metallodiporphyrins

Doi:10.1021/ja00047a016
(1992)
An efficient synthesis of 2,3-dihydroquinazolin-4(1H)-one derivatives under catalyst-free and solvent-free conditions

Doi:10.1002/jhet.592
(2011)

Article Doi