Journal of Organic Chemistry p. 1975 - 1976 (1991)
Update date:2022-08-02
Topics:
Hojo, Masaru
Masuda, Ryoichi
Kamitori, Yasuhiro
Okada, Etsuji
A study of the mechanism of the trifluoroacetylation of aryl vinyl sulfides was made.The rates of trifluoroacetylation of ArSCH=CH2, ArSCH=CD2, cis-ArSCH=CHD, and trans-ArSCH=CHD were determined.The results imply that this electrophilic substitution reaction proceeds by a single-step mechanism.
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