Electrophilic Substitution at an Olefinic Carbon Atom. Some Studies of the Mechanism of the Trifluoroacetylation of Aryl Vinyl Sulfides

DOI: 10.1021/jo00006a001

Source and publish data:

Journal of Organic Chemistry p. 1975 - 1976 (1991)

Update date:2022-08-02

Topics:

Authors:

Hojo, Masaru

Masuda, Ryoichi

Kamitori, Yasuhiro

Okada, Etsuji

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Article abstract of DOI:10.1021/jo00006a001

A study of the mechanism of the trifluoroacetylation of aryl vinyl sulfides was made.The rates of trifluoroacetylation of ArSCH=CH2, ArSCH=CD2, cis-ArSCH=CHD, and trans-ArSCH=CHD were determined.The results imply that this electrophilic substitution reaction proceeds by a single-step mechanism.

Full text of DOI:10.1021/jo00006a001

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