Synthesis and Characterization of Dinuclear Rhodium Complexes containig (Benzylthiomethyl)diphenylphosphine as the Bridging Ligand. Structure of the Novel Rhodium(II) Complex

DOI: 10.1039/DT9900003767

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3767 - 3772 (1990)

Update date:2022-08-04

Topics:

Authors:

Fuchita, Yoshio

Ohta, Yoshihisa

Hiraki, Katsuma

Kawatani, Masanori

Nishiyama, Nobuaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900003767

Treatment of <2> with 5 equivalents of PhCH2SCH2PPh2 (btmp) gave a mononuclear Vaska-type complex trans-, whereas the reaction with 2 equivalents of btmp afforded not the expected face-to-face complex but the chloro-bridged complex .The tetraphenylborate salt analogue BPh4 was obtained from the reaction of an ethanolic solution of ^- with 1 equivalent of btmp and NaBPh4.Treatment of n4> with 1 equivalent of btmp afforded the carbonyl-bridged dinuclear complex , while the above reaction performed in the presence of hydrochloric acid gave the novel dinuclear rhodium(II) complex (5).Complex (5) was also obtained from the reaction of an ethanolic solution of ^- and 1 equivalent of btmp.Crystals of (5) are monoclinic, space group C2/c, with a=14.064(3), b=19.364(4), c=16.930(5) Angstroem, β=116.67(2) deg, and Z=4; final R=0.036 for 3529 observed reflections.The structure shows that there is a metal-metal bond and the two μ-btmp ligands are co-ordinated to rhodium atoms cis to each other with a head-to-tail arrangement.The relationships among the synthesized complexes are discussed.

Full text of DOI:10.1039/DT9900003767

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis{μ-(benzylthiomethyl)diphenylphosphine}-1:2κ(2)P,S;1:2κ(2)S,P-bis{carbonyldichlororhodium(II)}(Rh-Rh)

Cas No:132232-28-1

R&D Labs maybe for 132232-28-1

Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai

Relevant to this article

Synthesis of (Z)-tributylstannyl enynes: Systematic studies of Sonogashira cross-coupling reactions between (E)-1-iodovinyl-1-tributylstannanes and terminal acetylenes using amines or tetrabutylammonium hydroxide (TBAOH) as activator

Doi:10.1016/j.tetlet.2011.06.004
(2011)
ONE-STEP CONVERSION OF FLAVANONES INTO ISOFLAVANONES: A NEW FACILE BIOMIMETIC SYNTHESIS OF ISOFLAVONES

Doi:10.1016/S0040-4039(00)88565-2
(1990)
Synthesis of 7-methyl-3-β-D-ribofuranosylwye, the putative structure for the hypermodified nucleoside isolated from archaebacterial transfer ribonucleic acids

Doi:10.1248/cpb.38.2656
(1990)
A new method for high-yield cyclopalladation of primary and secondary amines. Atom-efficient open-to-air inexpensive synthesis of Buchwald-type precatalysts

Doi:10.1021/om200464s
(2011)
Synthetic studies of huperzine A and its fluorinated analogues. 1. Novel asymmetric syntheses of an enantiomeric pair of huperzine A

Doi:10.1016/S0040-4020(98)00227-0
(1998)
Discovery of potent, soluble and orally active TRPV1 antagonists. Structure-activity relationships of a series of isoxazoles

Doi:10.1016/j.bmcl.2011.01.051
(2011)

Article Doi