Powerful Dienophiles for Asymmetric Diels-Alder Reactions: α-(2-exo-Hydroxy-10-bornylsulfinyl)maleimides

DOI: 10.1021/jo00006a005

Source and publish data:

Journal of Organic Chemistry p. 1983 - 1985 (1991)

Update date:2022-08-04

Topics:

Authors:

Arai, Yoshitsugu

Matsui, Makoto

Koizumi, Toru

Shiro, Motoo

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Article abstract of DOI:10.1021/jo00006a005

Enantiomerically pure N-substituted α-(2-exo-hydroxy-10-bornylsulfinyl)maleimides 1 have been synthesized diastereoselectively, and these dienophiles undergo Diels-Alder reactions readily with furan to give the corresponding cycloadducts with high diastereoselectivity.

Full text of DOI:10.1021/jo00006a005

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