Reactions of 1-aza-1,3-butadienes. A novel synthesis of 6-acetyl- and 6-methoxycarbonyl-5-methyl-2-cyclohexenones

DOI: 10.1055/s-1990-27072

Source and publish data:

Synthesis p. 993 - 994 (1990)

Update date:2022-08-04

Topics:

Authors:

Geirsson

Gudmundsdottir

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Article abstract of DOI:10.1055/s-1990-27072

The readily available N-tert-butyl-1-aza-1,3-pentadiene [N-(2-butenylidene)-2-methyl-2-propylamine] reacts with acetylacetone and methyl acetoacetate under acid-catalyzed reaction conditions to afford 6-acetyl- and 6-methoxycarbonyl-5-methyl-2-cyclohexenones, respectively, in good yield.

Full text of DOI:10.1055/s-1990-27072

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