A Novel Vinyl Anion Equivalent. An Extremely Short Synthesis of 2-Substituted 2-Cycloalkenones and Prostaglandin Key Intermediates via Destannylselenenylation

DOI: 10.1021/jo00037a035

Source and publish data:

Journal of Organic Chemistry p. 3145 - 3152 (1992)

Update date:2022-08-05

Topics:

Authors:

Kusuda, Shinya

Watanabe, Yoshihiko

Ueno, Yoshio

Toru, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00037a035

The preparation of a novel vinyl anion equivalent and a new destannylselenenylation procedure are described.The conjugate addition of (tributylstannyl)lithium to 2-(phenylseleno)-2-cycloalkenones, followed by the trapping of the resulting enolates with al

Full text of DOI:10.1021/jo00037a035

Products guided by the article

Product name:5-Heptynoic acid, 7-(6-oxo-1-cyclohexen-1-yl)-, methyl ester

Cas No:132570-81-1

R&D Labs maybe for 132570-81-1

China Synchem Technology Co.,Ltd

website:http://www.cnsynchem.com

Contact:+86-0552-4929311

Address:No.217 Daqing Road
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong
GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China
Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China

Relevant to this article

Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation

Doi:10.3762/bjoc.16.19
(2020)
Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes

Doi:10.1039/c1dt10752f
(2011)
Neighboring group participation in carbene chemistry. Effect of neighboring carboxylate group on carbene reactivities

Doi:10.1021/ja00177a033
(1990)
Synthesis, self-aggregation and biological properties of alkylphosphocholine and alkylphosphohomocholine derivatives of cetyltrimethylammonium bromide, cetylpyridinium bromide, benzalkonium bromide (C16) and benzethonium chloride

Doi:10.1016/j.ejmech.2013.05.033
(2013)
Chemomicrobial synthesis of (R)- and (S)-lavandulol

Doi:10.1016/j.tetlet.2011.06.072
(2011)
Michael-addition of malononitrile to 1,3-diaryl-2-propen-1-ones

Doi:10.1055/s-1990-27123
(1990)

Article Doi