A Novel Vinyl Anion Equivalent. An Extremely Short Synthesis of 2-Substituted 2-Cycloalkenones and Prostaglandin Key Intermediates via Destannylselenenylation

DOI: 10.1021/jo00037a035

Source and publish data:

Journal of Organic Chemistry p. 3145 - 3152 (1992)

Update date:2022-08-05

Topics:

Authors:

Kusuda, Shinya

Watanabe, Yoshihiko

Ueno, Yoshio

Toru, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00037a035

The preparation of a novel vinyl anion equivalent and a new destannylselenenylation procedure are described.The conjugate addition of (tributylstannyl)lithium to 2-(phenylseleno)-2-cycloalkenones, followed by the trapping of the resulting enolates with al

Full text of DOI:10.1021/jo00037a035

Products guided by the article

Product name:5-Heptynoic acid, 7-(6-oxo-1-cyclohexen-1-yl)-, methyl ester

Cas No:132570-81-1

R&D Labs maybe for 132570-81-1

Shanghai Micro-mega Industry Co., Ltd.

Contact:0086-21-34628682;57153848

Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Oren Hydrocarbons (Qingdao) Co., Ltd.

Contact:+86-532-68607667-801

Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,

Relevant to this article

Efficient method for propargylation of aldehydes promoted by allenylboron compounds under microwave irradiation

Doi:10.3762/bjoc.16.19
(2020)
Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes

Doi:10.1039/c1dt10752f
(2011)
Neighboring group participation in carbene chemistry. Effect of neighboring carboxylate group on carbene reactivities

Doi:10.1021/ja00177a033
(1990)
Synthesis, self-aggregation and biological properties of alkylphosphocholine and alkylphosphohomocholine derivatives of cetyltrimethylammonium bromide, cetylpyridinium bromide, benzalkonium bromide (C16) and benzethonium chloride

Doi:10.1016/j.ejmech.2013.05.033
(2013)
Chemomicrobial synthesis of (R)- and (S)-lavandulol

Doi:10.1016/j.tetlet.2011.06.072
(2011)
Michael-addition of malononitrile to 1,3-diaryl-2-propen-1-ones

Doi:10.1055/s-1990-27123
(1990)

Article Doi