STUDY OF THE REACTION OF SODIUM AMIDE IN LIQUID AMMONIA WITH HEXAHYDRO-(1H)-2-BENZAZONINIUM SALTS: ACCESS TO 2-AZA-(7)-METACYCLOPHANES

DOI: 10.1016/0040-4020(91)80006-N

Source and publish data:

Tetrahedron p. 47 - 52 (1991)

Update date:2022-08-02

Topics:

Authors:

Barbry, Didier

Spanneut, Damien

Hasiak, Bruno

Couturier, Daniel

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Article abstract of DOI:10.1016/0040-4020(91)80006-N

The rearrangement of hexahydro-(1H)-2-benzazoninium ylides in liquid ammonia yields a mixture of amines: metacyclophanes arise from Sommelet-Hauser transposition, alkenes from an Hofmann elimination, enamines from a process which is discussed here, and tw

Full text of DOI:10.1016/0040-4020(91)80006-N

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