Reactivity of Tris(Trimethylsilyl)silyl Radical with β-Alkenyloxyenones

DOI: 10.1016/0040-4039(95)01463-R

Source and publish data:

Tetrahedron Letters p. 7235 - 7238 (1995)

Update date:2022-08-03

Topics:

Authors:

Cossy, Janine

Salle, Laurent

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Article abstract of DOI:10.1016/0040-4039(95)01463-R

The addition of tris(trimethylsilyl)silyl radical on β-alkenyloxyenones generates an alkyl radical that can add onto the enone moiety.The tetrahydrofuranyl system so-obtained can undergo β-elimination leading to 3-alkylcycloalken-2-ones.

Full text of DOI:10.1016/0040-4039(95)01463-R

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