Reactivity of Tris(Trimethylsilyl)silyl Radical with β-Alkenyloxyenones

DOI: 10.1016/0040-4039(95)01463-R

Source and publish data:

Tetrahedron Letters p. 7235 - 7238 (1995)

Update date:2022-08-03

Topics:

Authors:

Cossy, Janine

Salle, Laurent

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01463-R

The addition of tris(trimethylsilyl)silyl radical on β-alkenyloxyenones generates an alkyl radical that can add onto the enone moiety.The tetrahydrofuranyl system so-obtained can undergo β-elimination leading to 3-alkylcycloalken-2-ones.

Full text of DOI:10.1016/0040-4039(95)01463-R

Products guided by the article

Product name:3-(5-hexenyloxy)-2-cyclohexen-1-one

Cas No:132638-30-3

R&D Labs maybe for 132638-30-3

Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
shanghai jinshan pharmaceutical Co.,Ltd

Contact:021-57363011，13681638167

Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

Relevant to this article

Synthesis of Chiral Homoallylic Nitriles by Iridium-Catalyzed Allylation of Cyanoacetates

Doi:10.1021/acs.joc.8b01632
(2018)
Stereocontrolled synthesis of β-hydroxyphenylalanine and β- hydroxytyrosine derivatives

Doi:10.1016/S0040-4020(01)85256-X
(1994)
Stereoselective Acetalization for the Synthesis of Liquid-Crystal Compounds Possessing a trans-2,5-Disubstituted 1,3-Dioxane Ring with Saturated Aqueous Solutions of Inorganic Salts

Doi:10.1021/acs.oprd.8b00408
(2019)
Doi:10.1039/jr9550003660
(1955)
Complexation of a Singlet Carbene by a Fluoroalkane. Modification of ¹:CHCO2Et Selectivity in Perfluorohexane Solution and ab Initio Calculations

Doi:10.1021/jo00090a020
(1994)
Discovery of liver-directed glucokinase activator having anti-hyperglycemic effect without hypoglycemia

Doi:10.1016/j.ejmech.2017.03.042
(2017)

Article Doi