A New Method for the Construction of the Pyrrole Ring by the Carbonylcobalt-Catalyzed Reaction of Trimethylsilyl Cyanide with Acetylenes. Its Scope and Limitations.

DOI: 10.1021/jo00006a038

Source and publish data:

Journal of Organic Chemistry p. 2166 - 2170 (1991)

Update date:2022-08-02

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Authors:

Chatani, Naoto

Hanafusa, Terukiyo

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Article abstract of DOI:10.1021/jo00006a038

The carbonylcobalt-catalyzed reaction of acetylenes with trimethylsilyl cyanide (1) to give 5-amino-1H-pyrrole-2-carbonitriles is described.Reaction of the symmetric internal acetylenes, 4-octyne (2a) and 2,9-dimethyl-5-decyne (2b), with 1 in the presence

Full text of DOI:10.1021/jo00006a038

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