Journal of Organic Chemistry p. 2166 - 2170 (1991)
Update date:2022-08-02
Topics:
Chatani, Naoto
Hanafusa, Terukiyo
The carbonylcobalt-catalyzed reaction of acetylenes with trimethylsilyl cyanide (1) to give 5-amino-1H-pyrrole-2-carbonitriles is described.Reaction of the symmetric internal acetylenes, 4-octyne (2a) and 2,9-dimethyl-5-decyne (2b), with 1 in the presence
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