Molecular Interactions of Polysilane and Unsaturated Nitrogen Compounds. Photochemical Addition of Disilene versus Silylene to Azobenzene

DOI: 10.1039/c39910000043

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 43 - 44 (1991)

Update date:2022-08-05

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Authors:

Sakakibara, Akihito

Kabe, Yoshio

Shimizu, Toshio

Ando, Wataru

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Article abstract of DOI:10.1039/c39910000043

Photochemical reaction of hexamesitylcyclotrisilane 1 or tetramesityldisilene 2 with azobenzene produces silanol 5 via hydrolysis of diazasilacyclopropane 3 and/or 1,2-diaza-3,4-disilacyclobutane 4; the structure of 4 has been confirmed by variable temperature 1H NMR spectroscopy and single-crystal X-ray diffraction, the existence of an Si2N2 ring system is demonstrated.

Full text of DOI:10.1039/c39910000043

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