KINETICS AND PRODUCTS OF THE REACTION OF DIAZO COMPOUNDS WITH SO2

DOI: 10.1007/BF00958833

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2257 - 2260 (1990)

Update date:2022-08-03

Topics:

Authors:

Nazarov, A. M.

Nikolaev, A. I.

Serenko, S. Yu.

Komissarov, V. D.

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Article abstract of DOI:10.1007/BF00958833

Data were obtained on the composition of products and kinetics of the reaction of SO2 with Ph(R)CN2 (R = Ph, Me) in solutions of isooctane, 1,4-dioxane, and ethanol at 295 K.A mechanism was proposed for the process in accordance with which the sulfene being formed participates in concurrent reactions with the starting reagents.The relative rate constants for the process stages were determined.

Full text of DOI:10.1007/BF00958833

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