A new synthetic route to (±)-thienamycin via 4-exo trigonal cyclisation of carbamoyl cobalt intermediates

DOI: 10.1016/0040-4039(91)80870-C

Source and publish data:

Tetrahedron Letters p. 259 - 262 (1991)

Update date:2022-08-05

Topics:

Authors:

Pattenden, Gerald

Reynolds, Stephen J.

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Article abstract of DOI:10.1016/0040-4039(91)80870-C

A new synthesis of (±)-thienamycin (1), based on elaboration of the key intermediate (12) in one step by heating a solution of the carbamoylcobalt salophen (11) in toluene, is described.

Full text of DOI:10.1016/0040-4039(91)80870-C

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