Silicon-carbon unsaturated compounds. XXX. Thermal isomerization of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)-1-silacyclopropene and 2-mesityl-2-(phenylethynyl)hexamethyltrisilane

DOI: 10.1016/0022-328X(91)83073-D

Source and publish data:

Journal of Organometallic Chemistry p. C20 - C22 (1991)

Update date:2022-07-30

Topics:

Authors:

Ishikawa, Mitsuo

Yuzuriha, Yukiharu

Horio, Tomoyuki

Kunai, Atsutaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(91)83073-D

The thermolysis of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)-1-silacyclopropene at 280 deg C affored 1-mesityl-3,3-dimethyl-4-phenyl-5-(trimethylsilyl)-1,3-disilacyclo-4-pentene and 1-mesityl-1,3-bis(trimethylsilyl)-1-silaindene.Similar thermolysis of 2-mesityl-2(phenylethynyl)hexamethyltrisilane produced the same products.

Full text of DOI:10.1016/0022-328X(91)83073-D

Products guided by the article

Product name:1H-1-Silaindene, 1-(2,4,6-trimethylphenyl)-1,3-bis(trimethylsilyl)-

Cas No:132999-49-6

R&D Labs maybe for 132999-49-6

Radiant Pharma & Tech Company

Contact:+86-511-88790000

Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

Direct arylation of imidazo[2,1-b]thiazoles and thiazoles with aryl iodides via CuCl₂/PPh₃-catalyzed C-H bond functionalization

Doi:10.1002/aoc.3263
(2015)
Rapid selective defunctionalization of the carbonyl group of α,β-unsaturated ketones with trialkoxylsilane/ZnX₂

Doi:10.1080/10426507.2010.536188
(2011)
Hybrid mesoporous silica nanoparticles with pH-operated and complementary H-bonding caps as an autonomous drug-delivery system

Doi:10.1002/chem.201402864
(2014)
Reactions of benzyldiphenylphosphine with Pd(II) sources on silica gel

Doi:10.1016/j.jorganchem.2011.06.026
(2011)
Synthesis and evaluation of heterocyclic catechol mimics as inhibitors of catechol-o-methyltransferase (COMT)

Doi:10.1021/ml500502d
(2015)
BF₃·SiO₂-catalyzed one-pot synthesis of α-aminophosphonates in ionic liquid and neat conditions

Doi:10.1016/j.tetlet.2011.07.027
(2011)

Article Doi