Silicon-carbon unsaturated compounds. XXX. Thermal isomerization of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)-1-silacyclopropene and 2-mesityl-2-(phenylethynyl)hexamethyltrisilane

DOI: 10.1016/0022-328X(91)83073-D

Source and publish data:

Journal of Organometallic Chemistry p. C20 - C22 (1991)

Update date:2022-07-30

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Authors:

Ishikawa, Mitsuo

Yuzuriha, Yukiharu

Horio, Tomoyuki

Kunai, Atsutaka

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Article abstract of DOI:10.1016/0022-328X(91)83073-D

The thermolysis of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)-1-silacyclopropene at 280 deg C affored 1-mesityl-3,3-dimethyl-4-phenyl-5-(trimethylsilyl)-1,3-disilacyclo-4-pentene and 1-mesityl-1,3-bis(trimethylsilyl)-1-silaindene.Similar thermolysis of 2-mesityl-2(phenylethynyl)hexamethyltrisilane produced the same products.

Full text of DOI:10.1016/0022-328X(91)83073-D

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