The Stereochemical Requirement in the Fragmentation of 9-Bromocamphor Derivatives. A New Class of Chiral Pool Elements Containing Asymmetric Quaternary Carbon Centers

Article abstract of DOI:10.1021/jo00008a010

The fragmentation of 9-bromobornan-2-ol derivatives is dependent on both the orientation and identity of the leaving group at the 2-position.This has led to a synthesis of compounds containing useful quaternary carbon centers in carbocyclic six-membered r