Tandem Radical Cyclization of Acyclic Homoallylic Xanthates; Cyclopentannulated γ-Thionolactone and γ-Lactones

DOI: 10.1021/jo00008a048

Source and publish data:

Journal of Organic Chemistry p. 2849 - 2853 (1991)

Update date:2022-08-03

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Authors:

Iwasa, Seiji

Yamamoto, Makoto

Kohmoto, Shigeo

Yamada, Kazutoshi

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Article abstract of DOI:10.1021/jo00008a048

The first tandem radical cyclization of linear homoallylic xanthates was explored.Homoallylic xanthates prepared from α,β-unsaturated esters were easily cyclized by tin hydride with an radical initiator to give the corresponding thionolactone annulated cy

Full text of DOI:10.1021/jo00008a048

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