Preparation of Anthraquinones from 10-Hydroxy-9-anthracenecarbonitriles Obtained from a Novel Aryne Annulation Reaction

DOI: 10.1021/jo00008a047

Source and publish data:

Journal of Organic Chemistry p. 2846 - 2849 (1991)

Update date:2022-08-03

Topics:

Authors:

Bhawal, Baburao M.

Khanapure, Subhash P.

Zhang, Hongming

Biehl, Edward R.

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Article abstract of DOI:10.1021/jo00008a047

A new method for brief regioselective synthesis of anthraquinones via the reaction of anions of ethyl cyanoacetate or the anions of 2-(carbethoxyaryl)acetonitriles with arynes is described.

Full text of DOI:10.1021/jo00008a047

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Product name:10-hydroxy-3,4,5,6-tetramethoxy-9-anthracenecarbonitrile

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