PALLADIUM(II) CATALYSED TANDEM -SIGMATROPIC SHIFT-1,3-DIPOLAR CYCLOADDITION PROCESSES IN OXIME O-ALLYL ETHERS

DOI: 10.1016/0040-4039(91)80875-7

Source and publish data:

Tetrahedron Letters p. 279 - 282 (1991)

Update date:2022-08-04

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Authors:

Grigg, Ronald

Markandu, Jasothara

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Article abstract of DOI:10.1016/0040-4039(91)80875-7

Oxime O-allyl ethers are equilibrated with the corresponding N-allyl nitrones on treatment with 10 molpercent PdCl2(MeCN)2 by a formal <2,3>-sigmatropic shift.The nitrones can be trapped both inter- and intra-molecularly by appropriate dipolarophiles to g

Full text of DOI:10.1016/0040-4039(91)80875-7

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