Single-molecule magnet behavior with a single metal center enhanced through peripheral ligand modifications

DOI: 10.1021/ja204562m

Source and publish data:

Journal of the American Chemical Society p. 15814 - 15817 (2011)

Update date:2022-08-05

Topics:

Authors:

Jurca, Titel

Farghal, Ahmed

Lin, Po-Heng

Korobkov, Ilia

Murugesu, Muralee

Richeson, Darrin S.

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Article abstract of DOI:10.1021/ja204562m

Bis(imino)pyridine pincer ligands in conjunction with two isothiocyanate ligands have been used to prepare two mononuclear Co(II) complexes. Both complexes have a distorted square-pyramidal geometry with the Co(II) centers lying above the basal plane. This leads to significant spin-orbit coupling for the d⁷ Co(II) ions and consequently to slow relaxation of the magnetization that is characteristic of Single-Molecule Magnet (SMM) behavior.

Full text of DOI:10.1021/ja204562m

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