Tetrahedron p. 895 - 905 (1991)
Update date:2022-08-04
Topics:
Nikishin, Gennady I.
Elinson, Michail N.
Makhova, Irina V.
Electrochemical oxidation of methyl ketones in methanoi in the presence of alkali metal bromides affords methyl carboxylates. Benzyl alkyl ketones are transformed under similar conditions into methyl 3-phenylalkanoates, while ketones lacking σ-benzyl or σ-methyl group are oxidized into σ-hydroxyketals.
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