Tetrahedron Letters p. 45 - 48 (1991)
Update date:2022-07-29
Topics:
Newcomb, Martin
Kumar, M. Udaya
Boivin, Jean
Crepon, Elisabeth
Zard, Samir Z.
Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates, whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.
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