CYCLIZATIONS AND INTERMOLECULAR ADDITIONS OF ALKOXYCARBONYLOXY RADICALS FROM N-HYDROXYPYRIDINE-2-THIONE CARBONATES

DOI: 10.1016/S0040-4039(00)71214-7

Source and publish data:

Tetrahedron Letters p. 45 - 48 (1991)

Update date:2022-07-29

Topics:

Authors:

Newcomb, Martin

Kumar, M. Udaya

Boivin, Jean

Crepon, Elisabeth

Zard, Samir Z.

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Article abstract of DOI:10.1016/S0040-4039(00)71214-7

Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates, whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.

Full text of DOI:10.1016/S0040-4039(00)71214-7

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