HIGHLY REGIO- AND DIASTEREOSELECTIVE FRIEDEL-CRAFTS ALKYLATION OF PHENOLS. SYNTHESIS OF 2-HYDROXYMANDELIC ESTERS

DOI: 10.1016/S0957-4166(00)82274-0

Source and publish data:

Tetrahedron Asymmetry p. 861 - 864 (1990)

Update date:2022-08-03

Topics:

Authors:

Bigi, F.

Casnati, G.

Sartori, G.

Dalprato, C.

Bortolini, R.

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Article abstract of DOI:10.1016/S0957-4166(00)82274-0

Ortho-hydroxyalkylation of phenol substrates was performed via coordinative complexes of metal phenolates with chiral glyoxylates: optically active 2-hydroxymandelic esters have been obtained with good yields and very high diastereoselectivity (up to 94pe

Full text of DOI:10.1016/S0957-4166(00)82274-0

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