Regioselectivity in lithium, sodium and potassium chloroallyl systems. An AB initio-theoretical and experimental study

DOI: 10.1016/S0040-4020(01)96196-4

Source and publish data:

Tetrahedron p. 8739 - 8752 (1991)

Update date:2022-08-03

Topics:

Authors:

Canepa Canepa

Tonachini

Venturello

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Article abstract of DOI:10.1016/S0040-4020(01)96196-4

The computed structural and electronic features of the title compounds describe the sodium and potassium systems as more inclined to CCl₂ regioselectivity with carbonyl electrophiles than the analogues lithium compounds. Some experimental results confirm this expectation.

Full text of DOI:10.1016/S0040-4020(01)96196-4

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