Regioselectivity in lithium, sodium and potassium chloroallyl systems. An AB initio-theoretical and experimental study

DOI: 10.1016/S0040-4020(01)96196-4

Source and publish data:

Tetrahedron p. 8739 - 8752 (1991)

Update date:2022-08-03

Topics:

Authors:

Canepa Canepa

Tonachini

Venturello

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96196-4

The computed structural and electronic features of the title compounds describe the sodium and potassium systems as more inclined to CCl₂ regioselectivity with carbonyl electrophiles than the analogues lithium compounds. Some experimental results confirm this expectation.

Full text of DOI:10.1016/S0040-4020(01)96196-4

Products guided by the article

Product name:[2,2-Dichloro-1-(4-chloro-phenyl)-but-3-enyloxy]-trimethyl-silane

Cas No:133617-10-4

R&D Labs maybe for 133617-10-4

Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Shanghai Cheerchem Co., Ltd.

Contact:86-21-50966856

Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Jinhua Haoyuan Chemical CO., LTD(expird)

Contact:86-579-82465583

Address:Jinhua,Zhejiang
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Guangxi Bonger Pharmaceutical Co., Ltd

website:http://napo.lookchem.com/

Contact:+86-18817331185

Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China

Relevant to this article

Carbanion addition to acetylenes: An efficient stereoselective route to α-methylene-γ-lactams

Doi:10.1016/S0040-4039(00)79668-7
(1991)
Novel proton acceptor immonium-type coupling reagents: Application in solution and solid-phase peptide synthesis

Doi:10.1021/ol701817u
(2007)
Synthesis, structure, DNA-binding properties, and antioxidant activity of copper(II) and cobalt(II) complexes with bis(N-allylbenzimidazol-2-ylmethyl) benzylamine

Doi:10.1007/s11243-011-9536-5
(2011)
A Series of hyperbranched polytriazoles containing perfluoroaromatic rings from AB₂-type monomers: Convenient syntheses by click chemistry under copper(I) catalysis and enhanced optical nonlinearity

Doi:10.1002/asia.201100379
(2011)
A formal synthesis of valiolamine from myo-inositol

Doi:10.1016/j.tet.2011.08.027
(2011)
An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule

Doi:10.1039/c1cc14664e
(2011)

Article Doi