Intramolecular [2+2] photocycloaddition of substituted isoquinolones: Enantioselectivity and kinetic resolution induced by a chiral template

DOI: 10.1002/anie.201103051

Source and publish data:

Angewandte Chemie - International Edition p. 8416 - 8419 (2011)

Update date:2022-08-04

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Authors:

Austin, Kerrie A. B.

Herdtweck, Eberhardt

Bach, Thorsten

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Article abstract of DOI:10.1002/anie.201103051

From simple to complex: Starting from easily accessible isoquinolones 1 (X=Br, OH), complex cyclobutane photoproducts such as compound 2 can be obtained with high enantioselectivity (88-96% ee) through the use of a chiral template. Compound 3, which was i

Full text of DOI:10.1002/anie.201103051

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