Stereodynamics and absolute configuration of stereolabile atropisomers in 2,2-dimethyl-1-aryl-1-indanols

DOI: 10.1002/chir.20988

Source and publish data:

Chirality p. 768 - 778 (2011)

Update date:2022-08-04

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Authors:

Casarini, Daniele

Mancinelli, Michele

Mazzanti, Andrea

Boschi, Francesca

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Article abstract of DOI:10.1002/chir.20988

We describe herein the investigation of the stereodynamic processes occurring in a series of 1-aryl-2,2-dimethylindanols, by dynamic NMR. When the aryl moiety is a mesityl or a 2-methyl-1-naphthyl, the rotational barrier exceeds the 25 kcal/mol, so that s

Full text of DOI:10.1002/chir.20988

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