
Tetrahedron p. 1157 - 1162 (1991)
Update date:2022-08-04
Topics:
Ramaswamy, Sowmianarayanan
Oehlschlager, Allan C.
Porcine pancreatic lipase (PPL) mediated resolution of 6-heptene-2-ol afforded the enantiomers in high optical purities.Alkylation products of the dianion of the 2-4'-hydroxypentyl-1,3-dithiane prepared from the enantiomers, followed by alkylative hydrolysis, afforded 97percent optically pure E-7-methyl-1,6-dioxaspiro<4,5>decane.
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(1994)