SYNTHESIS OF 3'-C-ETHYNYLNUCLEOSIDES OF THYMINE

DOI: 10.1016/S0040-4020(01)96914-5

Source and publish data:

Tetrahedron p. 1727 - 1736 (1991)

Update date:2022-08-02

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Authors:

Huss, Sophie

Heras, Federico G. De las

Camarasa, Maria Jose

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Article abstract of DOI:10.1016/S0040-4020(01)96914-5

Reaction of 1-<2,5-di-O-(t-butyldimethylsilyl)-β-D-erythro-pentofuranos-3-ulosyl>thymine with HCCMgBr gives a (25:1) mixture of 3'-C-ethynyl nucleosides of thymine having β-D-xylo and β-D-ribo configuration.Reaction of 1-(2'-deoxy-5'-O-trityl-β-D-glycero-

Full text of DOI:10.1016/S0040-4020(01)96914-5

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