Direct synthesis of polysubstituted aluminoisoxazoles and pyrazoles by a metalative cyclization

DOI: 10.1021/ol202389u

Source and publish data:

Organic Letters p. 5664 - 5667 (2011)

Update date:2022-08-02

Topics:

Authors:

Jackowski, Olivier

Lecourt, Thomas

Micouin, Laurent

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Article abstract of DOI:10.1021/ol202389u

Alumino-heteroles are obtained from simple precursors in a fully chemo- and regioselective manner by a metalative cyclization. The carbon-aluminum bond is still able to react further with several electrophiles, without the need of transmetalation. This sy

Full text of DOI:10.1021/ol202389u

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