Tetrahedron p. 1757 - 1762 (1986)
Update date:2022-07-29
Topics:
Stober, Reinhard
Musso, Hans
Osawa, Eiji
On catalytic hydrogenation over Pd-C under normal conditions cubane (10) takes up 3 mol of hydrogen in a few hours.Bicyclo<2.2.2>octane (13) is formed as the main product, and tetracyclo<4.2.0.02.5.03.8>octane (11, secocubane) and tricyclo<4.2.0.02.5>octane (12, nortwistbrendane) have been identified as intermediates.The hydrogenolysis of dimethyl 1,4-cubane dicarboxylate, as well as cuneane derivatives, have also been studied.Results are discussed in terms of strain relief calculated by the molecular mechanics method for cubane-like structures.
View MoreXinchang Jiu Xin Pharmaceutical Co., Ltd
website:http://www.jiuxinpharm.com
Contact:86 137 5756 8585
Address:Poyang industry Park
Wuxi Morality Chemical Co., Ltd(expird)
Contact:
Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Contact:18669908765
Address:Zibo City, Shandong Province, P.R.China
Contact:+86-577-65618087-605
Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Luoyang Aoda chemical Co.,Ltd.
Contact:+86-379-67518785 67516588
Address:MiaoWan industry district,YanShi City,Henan,China
Doi:10.1021/jo00012a021
(1991)Doi:10.1016/j.poly.2017.02.008
(2017)Doi:10.1016/j.tetlet.2011.08.007
(2011)Doi:10.1016/j.bmc.2011.07.033
(2011)Doi:10.1021/jo2012384
(2011)Doi:10.1021/om00051a022
(1991)
