Tetrahedron p. 1757 - 1762 (1986)
Update date:2022-07-29
Topics:
Stober, Reinhard
Musso, Hans
Osawa, Eiji
On catalytic hydrogenation over Pd-C under normal conditions cubane (10) takes up 3 mol of hydrogen in a few hours.Bicyclo<2.2.2>octane (13) is formed as the main product, and tetracyclo<4.2.0.02.5.03.8>octane (11, secocubane) and tricyclo<4.2.0.02.5>octane (12, nortwistbrendane) have been identified as intermediates.The hydrogenolysis of dimethyl 1,4-cubane dicarboxylate, as well as cuneane derivatives, have also been studied.Results are discussed in terms of strain relief calculated by the molecular mechanics method for cubane-like structures.
View Morewebsite:http://www.chemdow.com
Contact:0086-10-82435335
Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Huangshan Honghui Pharm Technology Co., Ltd.(expird)
website:http://www.honghuichem.com
Contact:18855958372
Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Chengdu Cogon Bio-tech Co., Ltd.
Contact:86-28-85171192
Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
website:http://www.trustwe.com
Contact:+86-21-61551413
Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Doi:10.1021/jo00012a021
(1991)Doi:10.1016/j.poly.2017.02.008
(2017)Doi:10.1016/j.tetlet.2011.08.007
(2011)Doi:10.1016/j.bmc.2011.07.033
(2011)Doi:10.1021/jo2012384
(2011)Doi:10.1021/om00051a022
(1991)
