Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 421 - 429 (1991)
Update date:2022-08-05
Topics:
Belostotskii, A. M.
Shapiro, A. B.
Triacetonamine was used to synthesize a series of highly substituted 4-piperidones and 4-piperidols.The spatial configuration of these compounds was determined.The anionoid addition to the carbonyl group of these piperidones proceeds through highly stereoselective equatorial attack.The position of the chair-chair-twist conformational equilibrium was determined for the polysubstituted 4-piperidols.
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