VO(OR)Cl2-induced cyclization of diketene via ring opening

DOI: 10.1016/0022-328X(91)83148-W

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1991)

Update date:2022-08-04

Topics:

Authors:

Hirao, Toshikazu

Fujii, Takashi

Ohshiro, Yoshiki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(91)83148-W

Diketene undergoes a VO(OR)Cl2-induced cyclization with styrenes via ring opening to give 3-alkoxycarbonyl-2-methyl-5-phenyl-4,5-dihydrofurans.Desilylative aromatization to the furans is observed in the reaction with α-trimethylsilylstyrene.

Full text of DOI:10.1016/0022-328X(91)83148-W

Products guided by the article

Product name:2-Methyl-5-phenyl-5-trimethylsilanyl-4,5-dihydro-furan-3-carboxylic acid isopropyl ester

Cas No:133942-55-9

R&D Labs maybe for 133942-55-9

HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province
Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Shanxi Tongji Pharmaceuticals Co., Ltd.

Contact:+86-359-3024784

Address:Xikuang South Road, Ruicheng County , Shanxi
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)

Relevant to this article

Synthesis of Potential Agonists and Antagonists for Central Glutamate Receptors by a Novel 'Ring Switching' Process

Doi:10.1039/c39910000314
(1991)
Optical Control of Cytokine Production Using Photoswitchable Galactosylceramides

Doi:10.1002/chem.201905279
(2019)
Stereoregular polycarbonate synthesis: Alternating copolymerization of CO₂ with aliphatic terminal epoxides catalyzed by multichiral cobalt(III) complexes

Doi:10.1002/pola.24945
(2011)
Synthesis and antimicrobial activity of some new 5-(3-chloro-1- benzothiophen-2-YL)-1,3,4-oxadiazole-2-thiol and their derivatives

Doi:10.1080/10426507.2011.586905
(2011)
Reactions of N-P^III-Phosphorylated trifluoroacetamides with (ethoxycarbonyl)triphenylmethylide

Doi:10.1007/s11176-005-0430-8
(2005)
Novel piperidine-fused benzoxazino- and quinazolinonaphthoxazines - Synthesis and conformational study

Doi:10.1016/j.tet.2012.05.048
(2012)

Article Doi