Synthesis of 2-(Trimethylsilyl)ethyl Benzenesulfenate and Benzeneselenenate and Their Reaction with Some Electrophiles in the Presence of Tetrabutylammonium Fluoride

DOI: 10.1246/bcsj.64.702

Source and publish data:

Bulletin of the Chemical Society of Japan p. 702 - 704 (1991)

Update date:2022-07-29

Topics: Synthesis Electrophiles Reaction Experimental Chemical terms

Authors:

Oida, Tatsuo

Ohnishi, Atsushi

Shimamaki, Toshiharu

Hayashi, Yoshiyuki

Tanimoto, Shigeo

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Article abstract of DOI:10.1246/bcsj.64.702

2-(Trimethylsilyl)ethyl benzenesulfenate was allowed to react with several halides in the presence of tetrabutylammonium fluoride (TBAF) to afford the corresponding phenyl sulfoxides as the main product.In the reaction of 2-(trimethylsilyl)ethyl benzeneselenenate and several halides with TBAF, the corresponding alcohols were obtained as the main product.

Full text of DOI:10.1246/bcsj.64.702

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