Tetrahedron p. 715 - 724 (1991)
Update date:2022-08-03
Topics:
Schaefer, Hans J.
Schneider, Roy
Primary hydroxy groups in pyranoses are oxidized in excellent yields to the corresponding carboxylic acids. In furanose 3 the yield of acid is only moderate. Secondary hydroxy groups are inert, aside from lactols. The different reactivity of secondary and primary hydroxy groups allows the chemoselective oxidation of 8 and 10.
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Doi:10.1021/acs.orglett.5b00711
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(2003)
