Electrooxidative C-S cleavages as a neutral deprotection for carbocxylic acids

DOI: 10.1016/S0040-4020(01)87075-7

Source and publish data:

Tetrahedron p. 867 - 876 (1991)

Update date:2022-08-03

Topics:

Authors:

Kimura Kimura

Matsubara

Yamamoto

Sawaki Sawaki

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Article abstract of DOI:10.1016/S0040-4020(01)87075-7

C-S Bond cleavages of S-t-butyl thioates (1) and 4-methoxyphenylthiomethyl esters (2) are achieved electrochemically in an indirect and direct manner, respectively, in aqueous acetonitrile, affording an efficient method for deprotection of carboxylic acids under neutral conditions.

Full text of DOI:10.1016/S0040-4020(01)87075-7

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