Medium-Ring γ-Epoxy Sulfones. Regio- and Stereochemistry of the Butyllithium-Promoted Transannular Epoxide Ring Opening

DOI: 10.1021/jo00014a035

Source and publish data:

Journal of Organic Chemistry p. 4513 - 4520 (1991)

Update date:2022-08-03

Topics:

Authors:

Cere, Vanda

Paolucci, Claudio

Pollicino, Salvatore

Sandri, Edda

Fava, Antonino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00014a035

Cyclic 8- and 9-membered E and Z γ-epoxy sulfones yield bicyclic hydroxy sulfones stereospecifically upon treatment with BuLi in THF.The distribution of regioisomeric products markedly depends on the metalation mode, portionwise or at once.This suggests t

Full text of DOI:10.1021/jo00014a035

Products guided by the article

Product name:cis-7-thiabicyclo<4.3.0>nonan-2α-ol 1,1-dioxide

Cas No:134333-94-1

R&D Labs maybe for 134333-94-1

xujianqiang

Contact:86-21-57725962

Address:shanghai
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China

Relevant to this article

In vitro binding studies of organotin(IV) complexes of 1,2-bis(1H- benzimidazol-2-yl)ethane-1,2-diol with CT-DNA and nucleotides (5′-GMP and 5′-TMP): Effect of the ancillary ligand on the binding propensity

Doi:10.1016/j.jorganchem.2011.08.007
(2011)
Synthesis of 3-arylthieno[2,3-b]-, -[2,3-c]- or -[3,2-c]pyridines utilizing an interrupted pummerer reaction

Doi:10.1055/s-0030-1260152
(2011)
Identification of racemic and chiral carbazole derivatives containing an isopropanolamine linker as prospective surrogates against plant pathogenic bacteria: In vitro and in vivo assays and quantitative proteomics

Doi:10.1021/acs.jafc.9b02036
(2019)
Lipophilic hydroxytyrosol esters: Fatty acid conjugates for potential topical administration

Doi:10.1021/np200405s
(2011)
Functionalized cyclopropenes as bioorthogonal chemical reporters

Doi:10.1021/ja3060436
(2012)
Cascade radical reaction induced by polarity-mismatched perfluoroalkylation

Doi:10.1055/s-0030-1261167
(2011)

Article Doi