Medium-Ring γ-Epoxy Sulfones. Regio- and Stereochemistry of the Butyllithium-Promoted Transannular Epoxide Ring Opening

DOI: 10.1021/jo00014a035

Source and publish data:

Journal of Organic Chemistry p. 4513 - 4520 (1991)

Update date:2022-08-03

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Authors:

Cere, Vanda

Paolucci, Claudio

Pollicino, Salvatore

Sandri, Edda

Fava, Antonino

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Article abstract of DOI:10.1021/jo00014a035

Cyclic 8- and 9-membered E and Z γ-epoxy sulfones yield bicyclic hydroxy sulfones stereospecifically upon treatment with BuLi in THF.The distribution of regioisomeric products markedly depends on the metalation mode, portionwise or at once.This suggests t

Full text of DOI:10.1021/jo00014a035

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