10.1002/asia.201900956
Chemistry - An Asian Journal
FULL PAPER
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shows that each monomeric unit consists of two S-atoms from
the two azobenzene-ligands that are coordinated to a silver ion.
The monomeric units are linked by bridging nitrates which impart
its linear structure. The polymer displays superior switching
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thermodynamic parameters for the isomerization process that
explained the faster switching of the polymer is due to the fact
that the energy of activation for the isomerization is lower in the
polymer compared to the ligand itself by 6 kcal/mol. The
coordination polymer was spin-coated on an ITO surface where
the trans form display a modest conductance. However, the cis
form obtained under the UV exposure displayed a drastic
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photo modulation of electronic mobility of a coordination polymer.
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The authors thank DST-SERB for financial support (Grant
number EMR/2017/003720). MS and SC are supported by
INSPIRE doctoral fellowship by DST-India. MSH is funded by a
CSIR-JRF. AG is supported by a INSPIRE undergraduate
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Keywords: azo compounds • photochromism • silver • molecular
electronics • electronic mobility
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