Novel method for generation of secondary organozinc reagent: Application to tandem carboncarbon bond formation reaction of 1,1-dibromoalkane

DOI: 10.1016/S0040-4039(00)74275-4

Source and publish data:

Tetrahedron Letters p. 1573 - 1576 (1991)

Update date:2022-08-06

Topics:

Authors:

Harada, Toshiro

Kotani, Yasuo

Katsuhira, Takeshi

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)74275-4

Reaction of 1,1-dibromoalkane (R¹CHBr₂) with trialkylzincate ((R²)₃ZnLi) followed by a palladium catalyzed coupling reaction of the resulting secondary organozinc reagent (R¹CH(R²)ZnL) with various electrophiles (El-X) afforded R¹CH(R²)El.

Full text of DOI:10.1016/S0040-4039(00)74275-4

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