Integrated chemical process. One-pot preparation of acetylenes by Peterson-sulfone elimination

DOI: 10.1246/cl.1997.1023

Source and publish data:

Chemistry Letters p. 1023 - 1024 (1997)

Update date:2022-08-03

Topics:

Authors:

Orita, Akihiro

Yoshioka, Naonori

Otera, Junzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1997.1023

Integration of silylation of α-sulfonyl carbanion, addition of the anion of the resulting α-silyl sulfone to aldehyde, Peterson elimination, and sulfone elimination leads to one-pot synthesis of acetylenes.

Full text of DOI:10.1246/cl.1997.1023

Products guided by the article

Product name:((E)-1-Benzenesulfonyl-3-phenyl-allyl)-trimethyl-silane

Cas No:134436-10-5

R&D Labs maybe for 134436-10-5

CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China

Relevant to this article

Design, synthesis and antibacterial activity of fluoroquinolones containing bulky arenesulfonyl fragment: 2D-QSAR and docking study

Doi:10.1016/j.ejmech.2011.09.011
(2011)
Site-selective DNA hydrolysis induced by a metal-free peptide nucleic acid-cyclen conjugate

Doi:10.1039/c1cc14185f
(2011)
Highly enantioselective conjugate addition-cyclization cascade reaction of malonates with o-hydroxycinnamaldehydes: Asymmetric synthesis of 4-substituted chromanols

Doi:10.1002/adsc.201100324
(2011)
C₃-symmetrical cinchonine-squaramide as new highly efficient, and recyclable organocatalyst for enantioselective michael addition

Doi:10.1002/adsc.201100066
(2011)
A radical cyclization approach to the formal total syntheses of platencin

Doi:10.1039/c1ob06155k
(2011)
Extended aromatic π-electron conjugated dyes with three azo bonds and either one or two azulen-1-yl moieties in molecule. Synthesis and basicity

Doi:10.1016/j.dyepig.2011.08.002
(2012)

Article Doi