Angewandte Chemie - International Edition p. 9120 - 9123 (2011)
Update date:2022-09-26
Topics:
Parsons, Andrew T.
Buchwald, Stephen L.
Activating the inactive: A copper-catalyzed allylic trifluoromethylation of unactivated terminal olefins proceeds under mild conditions to produce linear allylic trifluoromethylated products with high E/Z selectivity (see scheme). The reaction can be applied to a range of substrates bearing numerous functional groups. Furthermore, the reaction is scalable and amenable to a benchtop setup. Copyright
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Doi:10.1039/c1ob05959a
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(2011)
