THE UNSYMMETRICAL SILAKETAL AS A NEUTRAL, REMOVABLE TETHER FOR EFFECTING INTRAMOLECULAR DIELS-ALDER REACTIONS.

DOI: 10.1016/S0040-4039(00)92029-X

Source and publish data:

Tetrahedron Letters p. 1145 - 1148 (1991)

Update date:2022-08-03

Topics:

Authors:

Gillard, John W.

Fortin, Rejean

Grimm, Erich L.

Maillard, Michel,

Tjepkema, Michael

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92029-X

Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with high degree of a stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.

Full text of DOI:10.1016/S0040-4039(00)92029-X

Products guided by the article

Product name:(4aR,5R)-2,2-Diphenyl-4a,5,6,8a-tetrahydro-4H-benzo[1,3,2]dioxasiline-5-carboxylic acid ethyl ester

Cas No:134526-28-6

R&D Labs maybe for 134526-28-6

Hongyi Import & Export CO.,LTD

Contact:86-13319649499

Address:Nanzheng Neighborhood Commitees, Chongwen Office, Yongding District
JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province

Relevant to this article

Electrophilic substitution reactions of metallabenzynes

Doi:10.1021/ja207315h
(2011)
Multicomponent synthesis of 4-aminophthalazin-1(2 H)-ones by palladium-catalyzed isocyanide insertion

Doi:10.1021/jo401131p
(2013)
New multifunctional sulfonamide-containing azobenzene chromophores: Synthesis and photochromic properties

Doi:10.1016/j.dyepig.2011.07.008
(2012)
Iron oxide magnetic nanoparticles supported on amino propyl-functionalized KCC-1 as robust recyclable catalyst for one pot and green synthesis of tetrahydrodipyrazolopyridines and cytotoxicity evaluation

Doi:10.1002/aoc.5440
(2020)
A facile protocol for the synthesis of 4-aryl-1,4,7,8-tetrahydro-3,5- dimethyldipyrazolo[3,4-b:4′,3′-e]pyridine derivatives by a Hantzsch-type reaction

Doi:10.1007/s00706-011-0565-8
(2011)
Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative

Doi:10.1016/j.dyepig.2011.09.001
(2012)

Article Doi