Synthesis of sulfur-substituted α-stereogenic amides and ketones: Highly enantioselective sulfa-michael additions of 1,4-dicarbonylbut-2-enes

DOI: 10.1002/adsc.201100227

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Advanced Synthesis and Catalysis p. 2624 - 2630 (2011)

Update date:2022-07-29

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Authors:

Zhao, Fangli

Zhang, Wen

Yang, Yuanyong

Pan, Yuanhang

Chen, Wenchao

Liu, Hongjun

Yan, Lin

Tan, Choon-Hong

Jiang, Zhiyong

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Article abstract of DOI:10.1002/adsc.201100227

Conjugate addition to 1,4-dicarbonylbut-2-enes will generate an α-stereogenic center with respect to one of the carbonyl groups, which informally, can be considered as an inversion of normal reactivity patterns or umpolung protocol. In this paper, the add

Full text of DOI:10.1002/adsc.201100227

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