Journal of the American Chemical Society p. 4926 - 4931 (1991)
Update date:2022-07-29
Topics:
Schultz, Arthur G.
Harrington, Roger E.
Chiral 2-substituted-2-cyclohexen-1-one 2a is prepared from 1a by Birch reduction followed by acid-catalyzed hydrolysis-olefin migration. Conjugate additions of organometallic reagents to 2a occur with good to excellent diastereoselectivities (Table I). E
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