Electrophilic amination: First direct transfer of NHBoc with Li t-butyl-N-tosyloxycarbamate

DOI: 10.1016/S0040-4039(00)79923-0

Source and publish data:

Tetrahedron Letters p. 2359 - 2362 (1991)

Update date:2022-07-30

Topics:

Authors:

Genet Genet

Mallart Mallart

Greck Greck

Piveteau

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Article abstract of DOI:10.1016/S0040-4039(00)79923-0

Lithium t-butyl-N-tosyloxycarbamate (LiBTOC) has been found to be an electrophilic aminating reagent. This species reacts with organometallic reagents, ester enolates and α-cuprophosphonates to provide primary amines as well as α-aminocarboxylic and phosphonic esters in their N-(Boc) protected form. (35-80% isolated yields).

Full text of DOI:10.1016/S0040-4039(00)79923-0

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