Tetrahedron Letters p. 2359 - 2362 (1991)
Update date:2022-07-30
Topics:
Genet
Mallart
Greck
Piveteau
Lithium t-butyl-N-tosyloxycarbamate (LiBTOC) has been found to be an electrophilic aminating reagent. This species reacts with organometallic reagents, ester enolates and α-cuprophosphonates to provide primary amines as well as α-aminocarboxylic and phosphonic esters in their N-(Boc) protected form. (35-80% isolated yields).
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