N-NITROHYDRAZINES AND THEIR SALTS

Article abstract of DOI:10.1007/BF00961361

A method was developed for the synthesis of functionally substituted N-nitrohydrazines by nonacid nitration of the respective silylhydrazines.It was shown that the stability of these compounds increases with increase in the number of electronegative substituents.The first representative of N,N'-dinitrohydrazines, i.e., N,N'-dinitro-N,N'-diacetylhydrazine, was synthesized.Some of the obtained N-nitrohydrazines are characterized by dissociation with the formation of diazenes.The action of nucleophilic reagents on functionally N,N'-disubstituted N-methyl-N'-nitrohydrazines gave the salts of N-nitrohydrazines.