
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 988 - 995 (1991)
Update date:2022-07-30
Topics:
Kalinin, A. V.
Apasov, E. T.
Ioffe, S. L.
Tartakovskii, V. A.
A method was developed for the synthesis of functionally substituted N-nitrohydrazines by nonacid nitration of the respective silylhydrazines.It was shown that the stability of these compounds increases with increase in the number of electronegative substituents.The first representative of N,N'-dinitrohydrazines, i.e., N,N'-dinitro-N,N'-diacetylhydrazine, was synthesized.Some of the obtained N-nitrohydrazines are characterized by dissociation with the formation of diazenes.The action of nucleophilic reagents on functionally N,N'-disubstituted N-methyl-N'-nitrohydrazines gave the salts of N-nitrohydrazines.
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